Asymmetric ring‐opening reactions of bicyclic alkenes have emerged as a transformative approach in modern synthetic chemistry. These reactions capitalise on the inherent ring strain of fused cyclic ...
The latest short science news items from C&EN. The researchers trigger the reaction with violet light. First, there is an electron transfer from an oxidant, a N-alkoxyphthalimide ester, to the ...
Oxidizing the end carbon atom of a terminal alkene to form an aldehyde, a process called anti-Markovnikov alkene oxidation, is difficult because the reaction is energetically unfavorable. The ...
Researchers synthesized weird molecules that exist in three dimensions, breaking Bredt's rule and helping to develop future ...
An artist’s rendition of the new catalytic method for asymmetric fragmentation of cyclopropanes. (Credit: YAP Co., Ltd.) An organic catalyst offers chemists precise control over a vital step in ...